Search results for "Sandwich compound"
showing 3 items of 3 documents
Metallatomsynthese, Eigenschaften und Struktur von μ 2 ‐(η 3 ,η 3 ‐Toluol)bis[(η 6 ‐toluol)eisen](Fe‐Fe)
1995
Metal Atom Synthesis, Properties, and Structure of μ2(η3,η3-Toluene)bis[(η6-toluene)iron](Fe-Fe) Metal atom cocondensation of iron atoms and toluene produces the mononuclear iron sandwich compound [(η6-toluene)(η4-toluene)Fe] 1. Complex 1 reacts with a palette of N-containing ligands such as primary, secondary, and tertiary amines as well as pyridine, pyrrolidine, and tmeda to form highly reactive instable intermediates. In the temperature range from -80 to -30°C, the proposed intermediates react with toluene to form the first homoleptic Fe/toluene complex μ2-(η3η3-toluene)-bis[(η6-toluene)iron](Fe-Fe) (3) regardless which N-containing ligand is used. Additionally, 3 is also formed when eth…
Iron(II) complexes of naphthalenes. X-ray structure of [cyclopentadienyl-iron(II)-η6-octamethylnaphthalene]PF6
1992
Abstract Complex ions [cyclopentadienyl-Fe(methylnaphthalene)]+ with 4 to 8 methyl substituents have been prepared from [CpFe(o-dichlorobenzene)]+ by a photochemical ligand exchange. Complexation shifts have been determined for 1H and 13C resonances of the η6-bonded naphthalenes. The X-ray structure of [CpFe(octamethylnaphthalene)]PF6 0.5 acetone has been determined. Crystals are monoclinic, the space group C2/c with unit-cell dimensions a = 10.689(4), b = 22.391(5), c = 20.550(4)A, β = 93.41(2)°, Z = 8. The structure determination established a distorted molecular geometry of the octamethylnaphthalene that is different from the free arene and its Cr(CO)3 complex.
Réactivité d'hydrures de tantalocène : insertion du soufre dans la liaison tantale-hydrogène
1997
Resume La recherche entreprise sur la reactivite des hydrures de tantalocene avec le soufre elementaire nous amene a la synthese de complexes monosoufres par une reaction d'insertion du soufre dans la liaison Ta-H. Des informations sont apportees sur le mecanisme de la formation de complexes a ligand (η2-S2) et la synthese du complexe Cp′2Ta(CO)(SH) est decrite.